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Samarium(III) molybdate

Samarium(III) molybdate is an inorganic chemical compound with the formula Sm2(MoO4)3. It is a salt composed of samarium in its +3 oxidation state and molybdate anions. It is a crystalline solid that belongs to the family of rare earth molybdates.

Properties:

The compound is known for its ferroelastic and ferroelectric properties. These properties arise from its crystalline structure and the presence of the samarium ions. Samarium(III) molybdate exhibits a phase transition at a specific temperature, affecting its physical properties. The exact transition temperature varies depending on the specific crystalline form and any doping present.

Synthesis:

Samarium(III) molybdate can be synthesized through various methods, including solid-state reactions and co-precipitation techniques. Typically, these methods involve reacting a samarium source, such as samarium oxide (Sm2O3), with a molybdenum source, such as molybdenum trioxide (MoO3), at high temperatures or in a solution. The reaction conditions are carefully controlled to obtain the desired crystalline phase and stoichiometry.

Applications:

Due to its ferroelastic and ferroelectric properties, samarium(III) molybdate has potential applications in electronic devices, sensors, and actuators. It has been investigated for use in non-volatile memory devices and as a component in piezoelectric materials. Research continues to explore its potential in other advanced technological applications.

Safety:

As with other rare earth compounds and molybdates, appropriate safety precautions should be taken when handling samarium(III) molybdate. While specific toxicity data may be limited, it is generally recommended to avoid ingestion, inhalation, and skin contact. Proper ventilation and personal protective equipment should be used during handling.